尹宏峰 研究员

尹宏峰 博士,研究员,博士生导师。主要从事燃料电池气体催化、电极材料合成与SOFC技术开发等研究。已在国际一流杂志PNAS, Chem. Comm., J. Phys. Chem. C, J. Mater. Chem. A等学术期刊上发表学术论文40余篇,申报与授权发明专利18件。近5年领导的团队先后参与承担了SOFC国家重点研发计划、SOFC科技部国际合作、气体催化国家973计划青年科学家专题子课题,参与承担了燃料电池国家自然科学基金重点项目,主持了国家自然科学基金面上项目、中国科学院STS区域重点项目等。组织并完成燃气预处理与尾气处理催化单元与5kw SOFC系统的整合工作,主持宁波市“科技创新2025”重点项目“5kW甲醇重整与PEMFC一体化系统集成关键技术研究与应用”项目,完成实施集燃烧启动与催化重整一体化的热电联供系统设计与控制技术,20kW-SOFC系统集成与示范技术等。

主持或参与项目:

1.“高效金属-氧化物复合催化剂的理性设计与性能调控”,科技部973计划青年科学家专项,方向负责人;
2.“高活性纳米复合物(Au-MOx)@m-SiO2介孔核壳结构的合成及其在高温氧化中的催化和抗烧结性研究” ,国家自然科学基金面上项目,主持;
3. 浙江省自然科学基金,主持
4.“合成气制乙二醇工艺技术开发” ,企业横向项目,主持
5.“甘油制1,3-丙二醇催化工艺技术开发”,企业横向项目,主持
6. “烯烃高值转化的高效催化工艺开发”,宁波市“科技创新2025”重大专项,主持。

发表文章:

[1] Q. Li, H.B. Yu, K.J. Li, H.F. Yin*, S.H. Zhou*, “Controlled Synthesis and Enhanced Catalytic Activity of Well-defined Close-contact Pd-ZnO Nanostructures”, Langmuir, accepted.

[2]M.M. Liu, W.Q. Tang, Y.S. Xu, H.B. Yu, H.F. Yin*, S.L. Zhao *, S.H. Zhou *,  “Pd-SnO2/Al2O3 heteroaggregate nanocatalysts for selective hydrogenations of p-nitroacetophenone and p-nitrobenzaldehyde”. Appl. Catal. A-General.  549(2018), 273-279.

[3]K.J. Li, J.X. Wei, H.B. Yu, P.Y. Xu, J.H. Wang, H.F. Yin, Martien A. C. Stuart, J.Y. Wang,* and S.H. Zhou*, “A Generic Method for Preparing Hollow Mesoporous Silica Catalytic Nanoreactors with Metal Oxide Nanoparticles inside Their Cavities”, Angewa. Chemie. Intl. Ed. 57(2018), 50, 16458-16463.

[4]X.Y. Liang, C.Z. Wu, X.L.Yu, W.X. Huang, H.F. Yin*, “Pd Doped La0.1Sr0.9TiO3 as High-Temperature Water-Gas Shift Catalysts: In-Situ Formation of Active Pd Phase”, Catal. Letters, 148(2018), 9, 2830-2838. 

[5]M. Liu, W. Tang, Z. Xie, H. Yu, H. Yin, Y. Xu,* S. Zhao*, S. Zhou*, “Design of Highly Efficient Pt-SnO2 Hydrogenation Nanocatalysts using Pt@Sn Core−Shell Nanoparticles”,ACS Catal. 7(2017), 3, 1583–1591.

[6] X.L. Yu, H.B. Yu, Z. Lim, G.M. Yang, Z.H. Xie, S.H. Zhou, H.F. Yin* “Size-controlled synthesis of thermal stable single-cored Ru@H-SiO2 core-shell nanoparticles”,Chemical Physics Letters,654 (2016), 103-106.

[7] Z. Lim, C.Z. Wu, W.G. Wang, K. Choy*, H.F. Yin* “Porosity effect on ZrO2 hollow shells and hydrothermal stability for catalytic steam reforming of methane” J. Mater. Chem. A, 4(2016), 153–159

[8] Z. Lim, C.Z. Wu, W.G. Wang, K. Choy*, H.F. Yin* “A novel and anti-agglomerating Ni@yolk–ZrO2 structure with sub-10 nm Ni core for high performance steam reforming of methane” RSC Advances, 5(2015), 61925–61932.

[9] L.J. Hu; C. Zhou; C.Z. Wu; H.F. Yin*; S.H. Zhou and W.G. Wang, “Fe, Pd co-incorporated LaCoO3 perovskites: modification of thermal stability and catalytic activity for gasoline vehicle exhausts purification.” Eur. J. Inorg. Chem. 13(2015), 2317–2322.

[10]C. Zhou; Y.X. Zhang; L.J. Hu; H.F. Yin*; W.G. Wang, “Synthesis, characterization and catalytic activity of La0.8Sr0.2Co1-xMnxO3 (x=0.0, 0.1, 0.3, 0.5) perovskite oxides for three way catalysis.” Chem. Eng. Tech., 38(2015), 291-296.

[11]C. Zhou; Z.J. Feng; Y.X. Zhang; L.J. Hu; R. Chen; B. Shan*; H.F. Yin*; W. Wang; A. Huang, “Enhanced catalytic activity for NO oxidation over Ba doped LaCoO3 catalyst.” RSC Advances, 5(2015), 28054-28059.

[12]C. Zhou, X. Liu, C.Z. Wu, Y.W. Wen, Y.J. Xue, R. Chen, Z.L. Zhang, B. Shan,* H.F. Yin* ,W.G. Wang, “NO oxidation catalysis on copper doped hexagonal phase LaCoO3: a combined experimental and theoretical study”Phys.Chem.Chem.Phys.,16(2014) 5106-5112.

[13] C.Z. Wu, Z.Y Lim, C. Zhou, W.G. Wang, S.H. Zhou, H.F. Yin* , Y.J. Zhu,“A Soft-templated method to synthesize Sinteringresistant Au-mesoporous-silica Core-Shell nanocatalysts with Sub-5 nm Single-core, Chem. Comm. 49(2013), 31, 3215-3217.

[14] Y.B. Hu, K. Tao,  C.Z. Wu, C. Zhou, H.F. Yin*, S.H. Zhou*, Size-Controlled Synthesis of Highly Stable and Active Pd@SiO2 Core-Shell Nanocatalysts for Hydrogenation of Nitrobenzene” J. Phys. Chem. C, 117(2013),17, 8974-8982.

[15] Z.B. Peng, H. Miao, H.F. Yin, C. Xu, W.G. Wang “PEG-assisted Solid State Synthesis and Characterization of Carbon-Coated Li2MnSiO4 Cathode Materials for Lithium Ion Battery” Intl. J. Electronchem. Sci., 8(2013) 903-913.

[16] 彭振博,苗鹤,尹宏峰,赵文光,王蔚国, 喷雾干燥-高温固相法合成锂离子电池正极材料-Li2MnSiO4的研究,材料导报,2012,26(24) 46-49.

[17] H.F. Yin, Z. Ma, M.F. Chi, S. Dai, Heterostructured catalysts prepared by dispersing Au@Fe2O3 core-shell structures on supports and their performance in CO oxidation, Catalysis Today 160 (2011) 87-95.

[18] H.F. Yin, Z. Ma, H.G. Zhu, M.F. Chi, S. Dai, Evidence for and mitigation of the encapsulation of gold nanoparticles within SiO2 matrix upon calcining Au/SiO2 catalysts at high temperatures: implication to catalyst deactivation, Applied Catalysis A: General 386 (2010) 147-156.

[19] Z. Ma, H.F. Yin, S. Dai, Influence of preparation methods on the performance of metal phosphate-supported gold catalysts in CO oxidation, Catalysis Letters 138 (2010) 40-45.

[20] H.F. Yin, Z. Ma, M.F. Chi, S. Dai, Activation of dodecanethiol-capped gold catalysts for CO oxidation by treatment with KMnO4 or K2MnO4, Catalysis Letters 136 (2010) 209-221.

[21] E.W. Hagaman, J. Jiao, B.H. Chen, Z. Ma, H.F. Yin, S. Dai, Surface alumina species on modified titanium oxide: a solid-state 27Al MAS and 3QMAS NMR investigation of catalyst supports, Solid State Nuclear Magnetic Resonance 37 (2010) 82-90.

[22] Z. Ma, H.F. Yin, S. Dai, Performance of Au/MxOy/TiO2 catalysts in water-gas shift reaction, Catalysis Letters 136 (2010) 83-91.

[23] W. Dmowski , H.F. Yin, S. Dai, S.H. Overbury , T. Egami, Atomic Structure of Au Nanoparticles on a Silica Support by an X-ray PDF Study” Journal of Physical Chemistry C, 114(2010), 6983-6988.

[24] J.N. Zhang, Z. Ma, J. Jiao, H.F. Yin, W.F. Yan, E.W. Hagaman, J.H. Yu, S. Dai Surface functionalization of mesoporous silica SBA-15 by liquid-phase grafting of zirconium phosphate. Microporous Mesoporous Materials 129(2010), 200-209.

[25] C. Wang, H.F. Yin, S. Dai, S.H. Sun, A General Approach to Noble Metal-Metal Oxide Dumbbell Nanoparticles and Their Catalytic Application for CO Oxidation”, Chemistry of Materials, 22(2010), 3277-3282.

[26] C. Bouvy, G.A. Baker, H.F. Yin, S. Dai. Growth of Gold Nanosheets and Nanopolyhedra in Pyrrolidinium-Based Ionic Liquids: Investigation of the Cation Effect on the Resulting Morphologies. Crystal Growth & Design 10(2010), 1319-1322.

[27] J.N. Zhang, Z. Ma, J. Jiao, H.F. Yin, W.F. Yan, E.W. Hagaman, J.H. Yu, S. Dai, Layer-by-layer grafting of titanium phosphate onto mesoporous silica SBA-15 surfaces: synthesis, characterization, and applications, Langmuir 25 (2009) 12541-12549.

[28] S.H. Zhou, Z. Ma, H.F. Yin, Z.L. Wu, B. Eichhorn, S.H. Overbury, S. Dai, Low-temperature solution-phase synthesis of NiAu alloy nanoparticles via butyllithium reduction: influences of synthesis details and application as the precursor to active Au-NiO/SiO2 catalysts through proper pretreatment, Journal of Physical Chemistry C 113 (2009) 5758-5765.

[29] C. Wang, H.F. Yin, R. Chan, S. Peng, S. Dai, S.H. Sun, One-Pot Synthesis of Oleylamine Coated AuAg Alloy NPs and Their Catalysis for CO Oxidation, Chemistry of Materials, 21(2009), 433-435.

[30] S. Peng, Y.M. Lee, C. Wang, H.F. Yin, S. Dai, S.H. Sun, A Facile Synthesis of Monodisperse Au Nanoparticles and Their Catalysis of CO Oxidation, Nano Research, 1(2008), 229-234.

[31] Z. Ma, H.F. Yin, S.H. Overbury, S. Dai, Metal phosphates as a new class of supports for gold nanocatalysts, Catalysis Letters 126 (2008) 20-30.

[32] S.H. Zhou, H.F. Yin, V. Schwartz, Z.L. Wu, D. Mullins, B. Eichhorn, S.H. Overbury, S. Dai. In Situ Phase Separation of NiAu Alloy Nanoparticles for Preparing Highly Active Au/NiO CO Oxidation Catalysts. ChemPhysChem 9(2008), 2475-2479.

[33] H.F. Yin, Z. Ma, S.H. Overbury, S. Dai, Promotion of Au(en)2Cl3-derived Au/fumed SiO2 by treatment with KMnO4, Journal of Physical Chemistry C 112 (2008) 8349-8358.

[34] H.F. Yin, C. Wang, H.G. Zhu, S.H. Overbury, S.H, Sun, S. Dai, Colloidal deposition synthesis of supported gold nanocatalysts based on Au-Fe3O4 dumbbell nanoparticles, Chemical Communications, 36(2008), 4357-4359

[35]  M.H. Chisholm, J.C. Gallucci, H.F. Yin. 18-Membered cyclic esters derived from glycolide and lactide: preparations, structures and coordination to sodium ions, Dalton Transactions, 2007, 4811-4821.

[36]  M.H. Chisholm, J.C. Gallucci, H.F. Yin. Cyclic-Esters and Cyclodepsipeptides Derived from Lactide and 2,5-Morpholinediones. Proceedings of National Academy of Science. U. S. A. (103)2006, 103, 15315-15320.

[37]  M.H. Chisholm, J.C. Gallucci, H.F. Yin, H.S. Zhen, Hongshi.  Arylzinc Alkoxides: [ArZnOCHPri2]2 and Ar2Zn3(OCHPri2)4 When Ar = C6H5, p-CF3C6H4, 2,4,6-Me3C6H2, and C6F5. Inorganic Chemistry 44(2005), 4777-4785.

[38] G. Li, F.F Zhang, H. Chen, H.F. Yin, H.L. Chen, S.Y. Zhang.   Determination of Co-C bond dissociation energies for organocobalt complexes related to coenzyme B12 using photoacoustic calorimetry. J. Chem. Soc, Dalton Transactions 2002, 105-110.

[39] F.F Zhang, G. Li, H.F. Yin, S.Y. Zhang, H.L. Chen. Photoacoustic studies on radical kinetics and enthalpy change for photolysis of methylcobalamin. Progress in Natural Science (11)2001, S330-S333.

[40] G. Li, F.F Zhang, H. Chen, H.F. Yin, H.L. Chen, S.Y. Zhang. Using time-resolved photoacoustic calorimetry to study triplet energy and lifetime for benzophenone-KI system. Chinese. Science Bulletin  45(2000), 45, 335-338.

[41] F.F Zhang, G. Li, H.F. Yin, H.L. Chen, S.Y. Zhang. Determination of Co-C bond dissociation energy for n-C4H9Co(Salen)H2O using photoacoustic calorimetry. Chinese Journal of Inorganic Chemistry 16(2000), 144-146.

申请专利:

[1]余小龙,尹宏峰,于洪波。用于加氢合成对氯苯胺反应的催化剂、其制备方法及应用。申请号:CN201610129732.X。公告号:CN105562032A,已授权。
[2]薛业建,王蔚国,尹宏峰,周陈。一种高性能低成本三元催化剂的制备方法。专利号:201110298424.7,已授权。
[3]许杰、尹宏峰。一种工业萘生产的精萘方法。申请号:201810201981.4
[4]尹宏峰、许杰。工业萘选择性加氢催化剂及其制备方法。申请号:201810201966.X。
[5]许杰、尹宏峰。一种精萘的生产方法。申请号:201810201980.X。
[6]许杰、尹宏峰。工业萘选择性加氢催化剂、其制备方法与应用。申请号:201810201419.1。
[7]尹宏峰、许杰。工业萘选择性加氢催化剂载体及其制备方法。申请号:201810201431.2。
[8]梁萧雅,尹宏峰,余小龙。My/LaxSr1-xTi1-yO3催化剂、其制法及应用。申请号:201810049803.4。
[9]席盼盼; 尹宏峰。一种可控的双金属核壳纳米结构、催化剂、其制法与应用。申请号:201810244656.6。
[10]尹宏峰,许杰。 一种加氢裂化催化剂及其制备方法与应用。申请号:201710629122.0。
[11]许杰、尹宏峰。 劣质油料的加氢处理催化剂及其制备方法与应用。申请号: 201710629137.7。
[12]尹宏峰、许杰。 一种加氢裂化催化剂及其制备方法与应用。申请号: 201710629122.0。
[13]尹宏峰、许杰。 处理劣质油料的加氢精制催化剂及其制备方法与应用。申请号: 201710629136.2。
[14]尹宏峰、许杰。一种加氢精制催化剂及其制备方法与应用。申请号:201710629489.2。
[15]许杰,尹宏峰。劣质油料生产柴油的方法及系统。申请号:201510581854.8。